邵天举
中共党员,博士,副教授,化学北楼N301
E-mail: shaotianju@htu.edu.cn
【教育经历】
2015.9~2020.6 河南大学,天然药物与免疫工程重点实验室,有机化学,理学博士,导师:江智勇教授。
2011.9~2015.6 蚌埠学院,生物与食品工程系,生物工程,工学学士。
2008.9~2011.6 郸城县第一高级中学(郸城一高)。
2005.9~2008.7 吴台镇第一初级中学(吴台一中)。
【工作经历】
2020.7-至今 河南师范大学,化学化工学院-有机化学研究所,副教授,江智勇教授团队。
【研究领域与兴趣】
可见光催化、绿色有机合成、自由基精准转化
【近年来主持的主要科研项目】
[4] 国家自然科学青年基金(22301066),2024.1-2026.12,主持,资助金额:30万;
[3] 河南省博士后项目资助,2022-2024年,主持,资助金额:5万;
[2] 河南省中央引导地方科技发展资金项目,参与(第二),资助金额:100万;
[1] 国际合作创新研究团队项目, 参与(第三),资助金额:720万。
【所获荣誉】
博士研究生国家奖学金(2019);河南师范大学“急难险重”先进个人(2020);河南师范大学优秀工会积极分子(2023);河南师范大学“三育人”先进个人(2023-2024)
【发表论文】
[11] Shao, T.; Li, Z.; Nie, F.; Li, Q.; Zhao, X.; Jiang, Z.* Leveraging electron donor–acceptor complexes for kinetic resolution in catalytic asymmetric photochemical synthesis. Nat. Chem. 2025, 17, 1722–1731. DOI: 10.1038/s41557-025-01973-y. https://www.nature.com/articles/s41557-025-01973-y
[10] Shao, T.; Ban, X.; Jiang, Z.* Book《Photocatalysis for Heterocycle Formation and Functionalisation》Chapt 2: Photoredox Catalytic Asymmetric Functionalization of Azaarene Derivatives. 2025, pp 41-66. Editor: Xiao, W.-J. Topics in Heterocyclic Chemistry. DOI: 10.1007/7081_2025_89. https://doi.org/10.1007/7081_2025_89
[9] Li, Q.; Zhao, X.; Yin, Y.; Shao, T.*; Jiang, Z.* Asymmetric Photoredox Catalytic Minisci-Type Reactions of α‑Bromide Amides. Org. Lett. 2025, 27, 1244−1249. https://pubs.acs.org/doi/10.1021/acs.orglett.4c04791
[8] Shao, T.; Nie, F.; Cao, S.; Li, Q.; Zhao, X.; Yin, Y.; Jiang, Z.* Kinetic Resolution of Racemic Radicals in Asymmetric Photoredox Minisci Reactions with Azaarenes for Precise Construction of Two Non-adjacent Stereocenters. J. Am. Chem. Soc. 2025, 147, 10002−10011. https://pubs.acs.org/doi/10.1021/jacs.5c01623
[7] Ma, C.; Shen, J.; Qu, C.; Shao, T.*; Cao, S.*; Yin, Y.; Zhao, X.; Jiang, Z.* Enantioselective Chemodivergent Three-Component Radical Tandem Reactions through Asymmetric Photoredox Catalysis. J. Am. Chem. Soc. 2023, 145 (36), 20141−20148. https://pubs.acs.org/doi/10.1021/jacs.3c08883
[6] Shao, T.*; Ban, X.; Jiang, Z.* α-Amino Acids: An Emerging Versatile Synthon in Visible Light-Driven Decarboxylative Transformations. Chem. Rec. 2023, e202300122. https://onlinelibrary.wiley.com/doi/10.1002/tcr.202300122
[5] Wang, G.; Li, L.; Jiang, Y.; Zhao, X.; Ban, X.; Shao, T.; Yin, Y.; Jiang, Z. Kinetic Resolution of Azaarylethynyl Tertiary Alcohols by Chiral Brønsted Acid Catalysed Phosphine-Mediated Deoxygenation. Angew. Chem. Int. Ed. 2023, 62, e202214838. https://onlinelibrary.wiley.com/doi/10.1002/anie.202214838
[4] Shao, T.; Li, Y.; Ma, N.; Li, C.; Chai, G.; Zhao, X.; Qiao, B.*; Jiang, Z.* Photoredox-Catalyzed Enantioselective α-Deuteration of Azaarenes with D2O. iScience 2019, 16, 410−419; https://www.sciencedirect.com/science/article/pii/S2589004219301890?via%3Dihub
[3] Shao, T.; Yin, Y.; Lee, R.; Zhao, X.; Chai, G.; Jiang, Z.* Sequential Photoredox Catalysis for Cascade Aerobic Decarboxylative Povarov and Oxidative Dehydrogenation Reactions of N-Aryl α-Amino Acids. Adv. Synth. Catal. 2018, 360, 1754−1760. (selected as the Very Important Publication and Cover Picture); https://advanced.onlinelibrary.wiley.com/doi/full/10.1002/adsc.201800135
[2] Shao, T.; Jiang, Z.* Visible Light Mediated Photocatalytic Aerobic Dehydrogenation: A General and Direct Approach to Access 2,3-Dihydro-4-Pyridones and 4-Quinolones. Acta Chim. Sinica, 2017, 75, 70−73. (Invited); https://sioc-journal.cn/Jwk_hxxb/CN/10.6023/A16080407
[1] Bai, X.; Zeng, G.; Shao, T.; Jiang, Z.* Catalytic enantioselective γ-selective additions of 2-allylazaarenes to activated ketones. Angew. Chem. Int. Ed. 2017, 56, 3684–3688. https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201700190
【发明专利】
[3] 邵天举,江智勇,赵筱薇 【可见光催化不对称反应制备手性2-氮杂芳烃酰胺的方法】专利号:ZL 2024 1 1910089.5,授权公告号:CN 119707806 B
[2] 江智勇,邵天举,赵筱薇,刘洋,乔保坤【一种可见光催化氨基酸脱羧合成1,2,3,4-四氢喹啉类化合物的方法】专利号:ZL201711174689.X,授权公告号:CN108017580B
[1] 江智勇,邵天举,孔慢慢,李江涛,尹艳丽 【一种可见光协同催化四氢喹啉类化合物氧化脱氢合成喹啉类化合物的方法】专利号:ZL201711173523.6,授权公告号:CN108017579B